| chloriolide, a 12-membered macrolide from chloridium virescens var. chlamydosporum (nrrl 37636). | a new 12-membered macrolide (chloriolide; 1) was obtained from solid-substrate fermentation cultures of chloridium virescens var. chlamydosporum that was originally isolated from decayed wood. the structure of 1 was determined by analysis of 1d nmr, 2d nmr, and ms data and confirmed by x-ray crystallographic analysis. the absolute configuration of 1 was assigned by application of the modified mosher method using the (r)- and (s)-mtpa derivatives of a rearrangement product obtained under standard ... | 2006 | 16643041 |