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oleanane-type triterpenoids from the leaves and twigs of fatsia polycarpa.seven new oleanane-type triterpenoids (1-7), named fatsicarpains a-g, and the known compounds 3a-hydroxyolean-11,13(18)-dien-28-oic acid (8) and 3a-hydroxyolean-11-en-28,13ß-olide (9) were isolated from the leaves and twigs of fatsia polycarpa on the basis of bioassay-guided fractionation. the structures of compounds 1-7 were elucidated through spectroscopic analyses and single-crystal x-ray crystallography of 1, 8, and 9. cytotoxicity against hepg2 2.2.15 and ags cells and antihepatitis b virus ...201121766884
biological activity of oleanane triterpene derivatives obtained by chemical derivatization.nine new derivatives of oleanane triterpenoids isolated from fatsia polycarpa hayata were synthesized through chemical transformations. acetylation was effected by reaction with acetic anhydride in pyridine to afford compounds 1-5, while compound 6 was obtained using 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride (edc·hcl) in ch2cl2. the others derivatives 7-9 were obtained in reactions of the corresponding triterpenoids with edc·hcl, 4-n,n-dimethylaminopyridine hydrochloride and 4- ...201324145793
anti-inflammatory effects and mechanisms of fatsia polycarpa hayata and its constituents.fatsia polycarpa, a plant endemic to taiwan, is an herbal medicine known for treating several inflammation-related diseases, but its biological function needs scientific support. thus, the anti-inflammatory effects and mechanisms of the methanolic crude extract (mce) of f. polycarpa and its feature constituents, that is, brassicasterol (a phytosterol), triterpenoids 3 α -hydroxyolean-11,13(18)-dien-28-oic acid (hoda), 3 α -hydroxyolean-11-en-28,13 β -olide (hoeo), fatsicarpain d, and fatsicarpai ...201324489593
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