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synthesis and characterization of 2,3-dibromopropyl-2,4,6-tribromophenyl ether (dpte) and structurally related compounds evidenced in seal blubber and brain.the unknown compound ubc-1 previously described as the major organobromine contamination in the blubber extract of a hooded seal (cystophora cristata) from the barents sea was identified as 2,3-dibromopropyl-2,4,6-tribromophenyl ether (dpte). dpte, which is the main component of the brominated flame retardant (bfr) bromkal 73-5 pe, was synthesized by electrophilic addition of bromine to allyl-2,4,6-tribromophenyl ether (ate). the chirality of dpte was proven by gas chromatographic enantioseparat ...200717396646
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