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naphthoquinone spiroketal with allelochemical activity from the newly discovered endophytic fungus edenia gomezpompae.chemical investigation of the mycelium of edenia gomezpompae, a newly discovered endophytic fungus isolated from the leaves of callicarpa acuminata (verbenaceae) collected from the ecological reserve el eden, quintana roo, mexico, resulted in the isolation of four naphthoquinone spiroketals, including three new compounds and palmarumycin cp2 (4). we elucidated the structures of the metabolites by extensive nmr spectroscopy studies, including dept, cosy, noesy, hsqc, hmbc, and chiroptical methods ...200818234248
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