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new verticillin and glisoprenin analogues from gliocladium catenulatum, a mycoparasite of aspergillus flavus sclerotiafour new compounds (1-4) have been isolated from solid-substrate fermentation cultures of the sclerotial mycoparasite gliocladium catenulatum. the structures of verticillins d (1), e (2), and f (3) were assigned on the basis of ms and nmr data and chemical derivatization. the structure of glisoprenin f (4) was assigned by analysis of ms and nmr results, and comparison of its spectral data to those of the known compound glisoprenin d (6).199910346956
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